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the structural instability in the primary particles is related to heterogeneous distribution of the anisotropic strain change, which results in the micro-scale gap in the secondary particles, which could be the origins and mechanism on the experimental observations of the micro-crack propagations 25, 26, 27, 28, 29 .

here we investigate the prospects for self-healing of the crack in a composite material. we used a gradient-hardenable epoxy (lapis-lite®), which is designed for encapsulating fragile microcapsules and has been shown to be a good candidate for self-healing4 . by loading microcapsules with a highly viscous material that is transparent to x-rays, we have created crack-active composites. the self-healing process was monitored by synchrotron-based x-ray tomography, allowing to identify the release of the healing agent in real time and to track the crack length and crack mouth. we found that the microcapsules release their contents into the crack only when it is close to the crack mouth (within 2.5mm of the crack mouth), and that the microcapsules can repair cracks down to 0.8mm in width. after rupture of the microcapsules, the cracks heal and grow back to their original lengths in a few minutes.

in some applications, cracks in polymer composites are deliberately created to induce crack healing, thus creating a crack-active material. for example, self-healing epoxy composites are used to repair weak spots in fiber-reinforced composites to enhance their strength, or cracks are intentionally created to facilitate crack repair. self-healing epoxy resin forms a cohesive gel through cross-linking of the epoxy resin, which fills the crack and heals it. this process is normally triggered by the propagation of cracks, which causes damage to the epoxy resin. the damaged epoxy resin then transfers its healing agent into the crack to repair it. the crack is then closed and the composite material is strengthened. in some cases the cracks are deliberately created to induce crack healing and the cracks in the composite are intentionally created to facilitate crack repair. for example, self-healing epoxy resins are used to repair weak spots in fiber-reinforced composites to enhance their strength, or cracks are intentionally created to facilitate crack repair.

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