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The mechanical properties of two-dimensional (2D) materials have attracted considerable attention because they provide opportunities for energy storage and conversion. However, the determination of the fundamental linear and nonlinear nanomechanical properties is still a challenge due to the lack of an efficient platform for their study. Here, we report the first in-plane elastic constants, nonlinear deformation energy and nonlinear stress response of a mechanically exfoliated monolayer of MoS2. The elastic constants are calculated from the force-extension curves, while the nonlinear mechanical response is determined by a method combining the generalized V-notched beam theory with the atomic force microscopy measurements. The results show that the Young’s modulus and the out-of-plane strain of the monolayer are around 200 GPa and 2%, respectively. The in-plane strain decreases with increasing monolayer size, while the nonlinear deflection energy increases up to 7 orders of magnitude. This study demonstrates that mechanically exfoliated 2D materials offer an efficient platform for determining the fundamental properties of monolayer materials, and provides a benchmark to understand the fundamental mechanisms of linear and nonlinear mechanical response of these materials.This subproject is one of many research subprojects utilizing the resources provided by a Center grant funded by NIH/NCRR. The subproject and investigator (PI) may have received primary funding from another NIH source, and thus could be represented in other CRISP entries.

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