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Only registered users can make comments here.Cytotoxic metallomacrocycles and supramolecular assemblies.
A family of novel conjugate macromolecules containing a functional ruthenium metal center and a tethered supracatalytic assembly of aromatic polyethers have been prepared. The linear tetrapyrroles and tetrakis(imidazole) ligands bind to the [Ru(terpy)2](4+) metal center through a coordination of two amine nitrogen atoms and terminal metal carbonyl groups. The macrocycles and supramolecular assemblies in this family exhibit potent cytotoxicity to a panel of cancer cell lines, especially to human tumor cell lines derived from lymphomas. The monocyclic architectures are particularly effective, with IC50 values as low as 10(-11) M.Transanal surgical approach for rectal cancer: operative results and anorectal function after two years.
One-hundred one patients with rectal cancer underwent curative transanal excision with total mesorectal excision (TME) of the rectum. The five-year actuarial local recurrence rate was 19% and there was a fatal perioperative complication in 1%. Seven patients developed recurrence in 12 months, and only five patients (4.9%) had local recurrence 12 months after surgery. Anorectal man
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In the past decade, clinical pharmacists have advanced the status of the pharmacy technician and pharmacists in the care team. The traditional hierarchic structure is being replaced. Professional attitudes of pharmacy practice groups are also changing. The purpose of this study was to describe the attitudes of pharmacy students, residents, and faculty regarding the influence on clinical decision making by a pharmacist. An anonymous, 14-item questionnaire was distributed to pharmacy students, residents, and faculty attending a national workshop. The survey questions were: 1) What influence do you think a pharmacist’s participation in a patient’s care has on the other professionals in that patient’s care? 2) In the clinical decision-making process, do you consider a pharmacist’s input? 3) Do you recognize that your own decisions are influenced by the pharmacists’ input? 4) What factors influence the pharmacists’ input in the clinical decision-making process? 5) Do you feel that pharmaceutical care could improve the quality of care for patients? The study received Institutional Review Board approval. The data were tabulated and analyzed by frequencies and percentages. A total of 515 surveys were distributed, and 360 were returned (69%). The respondents included pharmacy students, residents, and faculty. The students and residents rated participation in patient care as having a high level of influence. Whereas faculty members rated this influence as low (P Effects of menopause on tooth loss pattern.
Oral health is one of the parameters in the quality of life of a population, because of its importance as a protective factor against other diseases. Menopause and bone loss are both related to a decrease in tooth loss; however, no studies have evaluated the effects of menopause on tooth loss patterns. The purpose of this study was to evaluate the tooth loss pattern before and after menopause in a population of peri- and postmenopausal women. This was a cross-sectional study
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